A ketone reacts with hydroxylamine to give

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A ketone reacts with hydroxylamine to give

  • A) a hydrazone
  • B) an alkanonitrile
  • C) a nitroso compound
  • D) an oxime

Correct Answer: D) an oxime

Explanation

A ketone is an organic compound containing a carbonyl group (C=O) bonded to two alkyl groups. When a ketone reacts with hydroxylamine (NH2OH), it forms a compound called an oxime.

Here is the general reaction for a ketone (R1CO-R2) reacting with hydroxylamine:

\(R_1CO-R_2 + NH_2OH \rightarrow R_1C(NOH)-R_2 + H_2O\)

In this reaction, the carbonyl group (C=O) of the ketone reacts with the hydroxylamine to form a new compound with a C=N-OH group, which is the characteristic functional group of an oxime. The other products of the reaction are water (H2O).

Therefore, the correct answer isOption D: an oxime.

Some other options mentioned are not formed during this reaction:

  • Hydrazone - formed when a ketone reacts with a hydrazine (NH2-NH2).
  • Alkanonitrile - contains a cyano group (C?N) and is not formed by the reaction of a ketone with hydroxylamine.
  • Nitroso compound - contains a nitroso group (N=O) and is not formed by the reaction of a ketone with hydroxylamine.


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