A ketone reacts with hydroxylamine to give
CHEMISTRY
POST UTME UI
A ketone reacts with hydroxylamine to give
- A) a hydrazone
- B) an alkanonitrile
- C) a nitroso compound
- D) an oxime
Correct Answer: D) an oxime
Explanation
A ketone is an organic compound containing a carbonyl group (C=O) bonded to two alkyl groups. When a ketone reacts with hydroxylamine (NH2OH), it forms a compound called an oxime.
Here is the general reaction for a ketone (R1CO-R2) reacting with hydroxylamine:
\(R_1CO-R_2 + NH_2OH \rightarrow R_1C(NOH)-R_2 + H_2O\)
In this reaction, the carbonyl group (C=O) of the ketone reacts with the hydroxylamine to form a new compound with a C=N-OH group, which is the characteristic functional group of an oxime. The other products of the reaction are water (H2O).
Therefore, the correct answer isOption D: an oxime.
Some other options mentioned are not formed during this reaction:
- Hydrazone - formed when a ketone reacts with a hydrazine (NH2-NH2).
- Alkanonitrile - contains a cyano group (C?N) and is not formed by the reaction of a ketone with hydroxylamine.
- Nitroso compound - contains a nitroso group (N=O) and is not formed by the reaction of a ketone with hydroxylamine.
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