(a) Explain briefly why \(_2^4He\) has a stable electron configuration compared to \(_4^9Be\) (b) Consider...

CHEMISTRY
WAEC 2019

(a) Explain briefly why \(_2^4He\) has a stable electron configuration compared to \(_4^9Be\)

(b) Consider the following elements: 1H and 3Li.

(i) State the number of electrons that an atom of each element would have after forming an ionic bond.

(ii) Give a reason for each of your answers stated in (b)(i).

(c) Statetwo factors that should be considered when siting a chemical industry.

(d) Statetwo advantages of using a catalyst instead of high temperatures in chemical reactions.

(e) Turpentine burns in chlorine according to the following equation:

C\(_{10}\)H\(_{16}\)\(_{(I)}\) + 8Cl\(_{2(g)}\) \(\to\) 10C\(_{(s)}\) + 16HCl\(_{(g)}\)

Calculate the mass of turpentine that would completely burn in 21.3 g of chlorine.

[Molar mass of chlorine = 71 gmol\(^{-1}\); Molar mass of Turpentine = 136 gmol\(^{-1}\)]

(f) What is cracking?

(g) Statetwo factors that may influence the value of electron affinity.

(h) What are carbohydrates?

(i) Statetwo differences between a simple sugar and starch.

(j) Write an equation to show the dissociation ofeach of the following acids:

(i) H\(_2\)CO\(_3\);

(ii) CH\(_3\)COOH.

Explanation

(a) \(_2^4He\) has its outermost / Valence shell fully filled with electrons / has maximum number of electrons in its outermost shell / duplet thus more stable whereas \(_4^9Be\) has incomplete filled outermost / valence shell hence less stable.

(b) (i) 1H - 2 electrons / zero

3Li - 2 electrons

(ii)1H - it accepts one electron/ donates one electron

3Li - it loses an electronto have a duplet shell

(c) - nearness to raw material / feed stock

- nearness to markets

- labour supply

- transportation

- availability of power supply

- government policy

- away from residential areas

- storage facilities for raw materials

- source of water supply

- conducive climate

(d) - saves money / the plant does not have to operate for long to produce

- reduces energy / reaction proceeds at a much lower temperature

- no undesirable products are formed / catalyst is specific in action

(e) From the equation:

8 moles of Cl\(_2\) reacts with 1 mole turpentine

1 mole of Cl\(_2\) = 71 g

8 moles = 8 x 71

= 568 g

\(\frac{21.3}{568}\)g will react with 21.3 x 136

= 5.1 g

OR

8 moles of Cl\(_2\) reacts with 1 mole turpentine



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