100cm 3 of oxygen and 10cm 3 of butane measured at room temperature and pressure
100cm3 of oxygen and 10cm3 of butane measured at room temperature and pressure were mixed and exploded. Determine the volume of the mixture when brought back to the original conditions of measurements.
- A) 125 cm3
- B) 110 cm3
- C) 75cm3
- D) none of the these
Correct Answer: C) 75cm3
Explanation
To answer this question, we need to first understand the balanced chemical equation of the reaction between butane and oxygen. Butane (C4H10) reacts with oxygen (O2) to form carbon dioxide (CO2) and water (H2O).
The balanced chemical equation for this reaction is:
2C4H10 + 13O2 ? 8CO2 + 10H2O
From the balanced equation, we can see that 2 moles of butane react with 13 moles of oxygen. To determine the volume of the mixture, we need to find the volume of the unreacted oxygen after the reaction.
We have 10 cm3 of butane, and since the ratio of butane to oxygen is 2:13, we can calculate that 10 cm3 of butane will react with 65 cm3 of oxygen.
Since we initially had 100 cm3 of oxygen, the remaining unreacted oxygen is:
100 cm3 - 65 cm3 = 35 cm3
Now, let's find the volume of the products of the reaction. From the balanced equation, we can see that the reaction produces 8 moles of CO2 and 10 moles of H2O for every 2 moles of butane. Since we have 10 cm3 of butane, the volume of CO2 produced is:
\(\frac{8}{2}\) * 10 cm3 = 40 cm3
The volume of H2O produced is:
\(\frac{10}{2}\) * 10 cm3 = 50 cm3
However, the water produced will condense at room temperature and pressure, so we only need to consider the volume of CO2 and unreacted oxygen in the mixture.
Therefore, the total volume of the mixture when brought back to the original conditions of measurements is:
35 cm3 (unreacted oxygen) + 40 cm3 (CO2) = 75 cm3
The correct option isOption C: 75 cm3.

