(a) State Faraday’s second law of electrolysis. (b) An electric charge of 9.6 x 10\(^4\)...

PHYSICS
WAEC 2009

(a) State Faraday’s second law of electrolysis.

(b) An electric charge of 9.6 x 10\(^4\) C liberates 1 mole of substance containing 6.0 x 10\(^{23}\) atoms. Determine the value of the electronic charge

Explanation

(a) If the same quantity of electricity is passed through different voltameters/electrolytes connected in series the masses of the substances liberated/deposited during electrolysis is (directly) proportional to their chemical equivalents.

OR The mass of an element deposited/liberated during electrolysis is (directly) proportional to the chemical equivalent of the element.

(b) Let e represent the electronic charge.

e =Faraday’s constant

Avogadro’s number

= 9.6 x 10\(^4\)

6. 0. x 10\(^{23}\)

= 1.60 x 10\(^{-19}\)C



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